Glyceryl Monooleate , also called GMO , glycerol 1-monooleate or grade designation XPO-4 , is identified by CAS No. 111-03-5 and EC No. 203-827-7 . The discrete monoester formula is C21H40O4 , but commercial grades can differ in mono-, di- and triglyceride distribution, free glycerol, free fatty acid and oxidation stability. Grade approval should use composition data, analytical limits and application testing rather than a blanket 99% claim.
Glyceryl Monooleate (GMO/XPO-4) CAS 111-03-5
- CAS: 111-03-5
- Synonyms: Glyceryl Monooleate, Glycerol 1-Monooleate, GMO, Monoolein, 2,3-Dihydroxypropyl Oleate, XPO-4
- Einecs: 203-827-7
- Molecular Formula: C₂₁H₄₀O₄
- Grade: For Glyceryl Monooleate (GMO/XPO-4) CAS 111-03-5, confirm the commercial grade code, ester composition, acid value, hydroxyl value, saponification value, water and physical form against the current TDS and COA.
- Package: State required quantity, physical form and destination; confirm the current bag or container, liner, net weight, temperature handling and transport requirements before quotation.
Product Description
Identity and physicochemical profile
| Item | Technical guidance |
|---|---|
| Product identity | Glyceryl monooleate; glycerol 1-monooleate |
| CAS / EC | 111-03-5 / 203-827-7 |
| Formula / molecular weight | C₂₁H₄₀O₄ / 356.5 g/mol |
| Commercial composition | Monooleate content and accompanying glycerides vary by grade and manufacturing route |
| Key quality controls | Monoester or monoglyceride content, acid value, hydroxyl value, saponification value, free glycerol, water, color and peroxide value where applicable |
| Terminology | Glyceryl monooleate is an ester, not a glyceryl oleate ether |
Applications and grade selection
Glyceryl monooleate is evaluated as a lipophilic co-emulsifier, emollient, dispersing aid or lubricity component. Performance depends on the commercial glyceride distribution, oil phase, oxidation control, dosage and process, so the XPO-4 designation must be linked to an actual specification.
- For personal care, compare sensory effect, emulsion stability, odor, color and impurity documentation for the offered grade.
- For lubricant or metalworking use, test friction, corrosion, emulsion behavior, oxidation and compatibility with the complete additive package.
- Food, pharmaceutical or other regulated use requires a specifically documented grade and independent compliance confirmation.
Storage and handling
Store tightly closed in a cool, dry area protected from heat, light, air exposure and incompatible oxidants. Follow the supplier’s instructions for warming, homogenization and sampling if the product thickens or separates.
Safety, documentation and procurement
Handle using the current SDS and site procedures. A quotation request should state the intended use, required monoglyceride or monooleate content, acid and peroxide limits, physical form, sample quantity, annual demand, package and destination.
For oleate ester emulsifier and lubricant comparisons, see PEG Monooleate, Polyglyceryl-4 Oleate, and PEG 400 Dioleate.
FAQ - Technical & Supply Chain
-
Q:
Does CAS 111-03-5 ensure the same monooleate content in every glyceryl monooleate grade?
A: No. Commercial glyceryl monooleate may contain monoglycerides with varying amounts of di- and triglycerides, so the CAS number does not establish a fixed ester distribution. For the intended formulation, compare monoglyceride or monooleate content, acid value, peroxide value, iodine value where relevant, physical form and the agreed test methods. -
Q:
Does CAS 111-03-5 by itself establish food, pharmaceutical or cosmetic grade?
A: No. The CAS identifies glyceryl 1-monooleate, while commercial GMO grades can differ in mono-, di- and triglyceride distribution, purity standards and intended use. State the required standard and destination market, then review the exact grade specification, COA, TDS, SDS and any applicable compendial or food-use documentation.
Ordering & Documentation
Key information for document requests, quotations, and supply planning.
Documents
COA, TDS, SDS/MSDS and packing details are available on request.
Quotation
Send the CAS number, grade, quantity, packing preference and destination.
Sample & Supply
Support is available for samples, trial orders, bulk and repeat supply.
Storage & Shipping
Product-specific conditions are confirmed before order.



