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  • Methyltetrahydrophthalic Anhydride (MTHPA) CAS 11070-44-3
  • Methyltetrahydrophthalic Anhydride (MTHPA) CAS 11070-44-3
  • Methyltetrahydrophthalic Anhydride (MTHPA) CAS 11070-44-3
  • Methyltetrahydrophthalic Anhydride (MTHPA) CAS 11070-44-3
  • Methyltetrahydrophthalic Anhydride (MTHPA) CAS 11070-44-3

Methyltetrahydrophthalic Anhydride (MTHPA) CAS 11070-44-3

Methyltetrahydrophthalic Anhydride (MTHPA) CAS 11070-44-3 is a high-performance liquid anhydride hardener chemically defined as a mixture of methylated tetrahydrophthalic isomers , functioning primarily as a curing agent for epoxy resins in electrical casting and composite manufacturing. Distinguished by its low viscosity at room temperature, light color, and long pot life, this curing agent is extensively utilized in the production of fiberglass reinforced plastics (FRP) pipes, wind turbine blades, and high-voltage electrical insulators (casting/potting). Unlike amine hardeners, MTHPA requires heat to cure but results in a polymer matrix with superior heat deflection temperature (HDT), excellent electrical insulation properties, and minimal shrinkage. We provide professional access to this material with competitive factory pricing and the ability to meet customized specifications (varying anhydride equivalent weights) for various manufacturing requirements. Our commitment to technical transparency ensures that every shipment is accompanied by comprehensive MSDS, TDS, COA documentation to support your quality assurance protocols, and we maintain capacity for consistent bulk supply to facilitate large-scale industrial operations.

  • CAS: 11070-44-3
  • Synonyms: MTHPA, Methyl tetrahydrophthalic anhydride, 4-Methyl-1,2,3,6-tetrahydrophthalic anhydride, Epoxy Anhydride Hardener, Liquid Anhydride Curing Agent
  • Einecs: 234-290-7
  • Molecular Formula: C9H10O3
  • Grade: Electronic Grade, Electrical Potting Grade.
  • Package: 220kg Iron Drum or 1200kg IBC Tank.
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Product Description

Methyl Tetrahydrophthalic Anhydride (MTHPA) is a high-performance, liquid alicyclic anhydride curing agent. It is widely preferred in the composite and electrical insulation industries due to its low viscosity at room temperature, low volatility, and long pot life. Unlike solid curing agents, MTHPA allows for easier handling and superior impregnation of complex components.

Our MTHPA series is synthesized via isomerization technology to ensure a stable structure. When cured with epoxy resins, it imparts excellent electrical properties, high heat resistance (high Tg), and superior mechanical strength to the final product. It is the gold standard hardener for casting, potting, and encapsulation applications.

Need technical advice on mixing ratios or accelerators? 📧 Email: info@industrochem.com

We offer customizable isomer ratios to fine-tune the freezing point and viscosity to match your specific climate and production environment.


Physicochemical Properties (Technical Data)

The following specifications represent our Standard Electronic Grade, typically used for high-voltage insulation and LED packaging.

PropertySpecification
AppearancePale yellow transparent liquid
Purity (by GC)≥99.0%
Anhydride Content≥41.0%−42.0%
Viscosity (25°C)20 – 50 mPa.s
Color (APHA/Pt-Co)≤100
Freezing Point≤−15S℃
Volatile Content≤1.0%
Free Acid≤1.0%
Specific Gravity (25°C)1.20 – 1.22 g/cm³
Gel Time (with accelerator)Customizable (e.g., >200 min at 100°C)

Applications

MTHPA is the critical hardener for applications requiring durability and electrical insulation:

1. Electrical Encapsulation & Potting:

  • Transformers & Coils: Used extensively for the impregnation and casting of ignition coils, high-voltage transformers, and mutual inductors due to its excellent dielectric properties.
  • Capacitors: Provides a hermetic seal that protects internal components from moisture and vibration.

2. Electronic Components:

  • LED Packaging: Its low color (APHA) and resistance to yellowing make it ideal for clear LED potting compounds.
  • PCBs: Used in insulating varnishes for printed circuit boards.

3. Composite Materials:

  • Wind Energy: Used in the vacuum infusion process for manufacturing wind turbine blades.
  • FRP Piping: Acts as a curing agent for filament-wound fiberglass pipes requiring chemical resistance.

4. Industrial Adhesives:

  • Formulates into high-strength structural adhesives for metal and ceramic bonding.

Quality Assurance (QA/QC)

At Industrochem, we ensure that every drop of MTHPA meets the stringent requirements of the electronics industry.

  • Isomer Control: We use advanced Gas Chromatography (GC) to monitor the distribution of isomers (3-methyl and 4-methyl), which directly impacts the viscosity and freezing point of the product.
  • Moisture Management: As anhydrides are sensitive to moisture (hydrolysis), our production lines are fully enclosed nitrogen-sealed systems. We strictly test Free Acid content to ensure no degradation has occurred.
  • Color Stability: For LED grade products, we perform rigorous UV aging tests and colorimetry to guarantee low yellowing index over time.

For the corresponding bisphenol-A epoxy resin system, see Epoxy Resin (Bisphenol A).

Storage, Handling & Safety

Storage Conditions:

  • Moisture Sensitivity: Critical. MTHPA reacts with atmospheric moisture to form acid. Containers must be kept tightly sealed at all times.
  • Temperature: Store in a cool, dry place between 5°C and 30°C. Although it has a low freezing point, avoiding extreme cold prevents crystallization.
  • Shelf Life: 12 months in original sealed packaging.

Safety Precautions (HSE):

  • Skin & Eye Contact: Anhydrides can be irritating to the skin, eyes, and respiratory system. May cause sensitization.
  • PPE Recommendations:
    • Respiratory: Wear a half-face respirator with organic vapor cartridges if ventilation is poor.
    • Skin: Butyl rubber or Neoprene gloves are recommended. Long-sleeved protective clothing is mandatory.
    • Eyes: Chemical splash goggles.
  • Handling: operate in a well-ventilated area. In case of contact with skin, wash immediately with soap and plenty of water.

Optimize your curing process with premium MTHPA.

Whether for high-voltage casting or clear LED potting, our technical team is ready to support your formulation.

👉 Get a Quote: info@industrochem.com

FAQ - Technical & Supply Chain

  • Q:

    What is Methyltetrahydrophthalic Anhydride MTHPA CAS 11070-44-3?

    A: MTHPA is a liquid alicyclic anhydride curing agent for epoxy resin systems. Its molecular formula is C9H10O3, with a molecular weight of about 166.17 g/mol.
  • Q:

    Why is MTHPA preferred over amine hardeners for electrical potting and encapsulation?

    A: MTHPA gives a controlled, low-exotherm cure, which reduces cracking and internal stress in large castings compared with fast room-temperature amine systems. It also provides good electrical insulation, heat resistance, and mechanical strength after heat curing.
  • Q:

    Does MTHPA require an accelerator when curing epoxy resin?

    A: Yes. MTHPA reacts slowly with epoxy by itself, so a tertiary amine accelerator such as BDMA or DMP-30 is normally used. Typical accelerator loading is about 0.5-3%, with curing usually carried out at elevated temperature.
  • Q:

    Why are different MTHPA isomer ratios offered?

    A: The isomer ratio influences crystallization tendency, freezing point, viscosity, and handling in different climates. Suppliers can adjust the ratio to provide a stable liquid that is easier to pump and impregnate into coils, transformers, and complex electrical components.
  • Q:

    What are the main applications of MTHPA CAS 11070-44-3?

    A: It is used for epoxy casting, potting, and encapsulation in electrical and electronic components such as transformers, coils, capacitors, and LED packages. It is also suitable for filament winding, pultrusion, and vacuum impregnation.

Ordering & Documentation

Key information for document requests, quotations, and supply planning.

Documents

COA, TDS, SDS/MSDS and packing details are available on request.

Quotation

Send the CAS number, grade, quantity, packing preference and destination.

Sample & Supply

Support is available for samples, trial orders, bulk and repeat supply.

Storage & Shipping

Product-specific conditions are confirmed before order.

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