Chemical products

Phosphorus Trichloride (PCl₃) CAS 7719-12-2

Phosphorus Trichloride (PCl₃), CAS 7719-12-2, is also known as trichlorophosphine. It is a phosphorus(III) chloride used in inorganic and organophosphorus synthesis. For procurement review, confirm the intended reaction route, water-exclusion and handling controls, offered form, and current specification, packaging, and applicable safety documentation.

  • CAS: 7719-12-2
  • Synonyms: Phosphorus trichloride; PCl₃; Phosphorus(III) chloride; Trichlorophosphine
  • Einecs: 231-749-3
  • Molecular Formula: PCl₃
  • Grade: Confirm current product specification
  • Package: Confirm packaging for the offered form
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Product Description

Product name: Phosphorus Trichloride (PCl₃)

CAS number: 7719-12-2

Phosphorus Trichloride (PCl₃) CAS 7719-12-2

Molecular formula: PCl₃

Molecular weight: 137.33 g/mol

EC number: 231-749-3

Other names: Phosphorus trichloride; PCl₃; Phosphorus(III) chloride; Trichlorophosphine

Chemical class: a phosphorus(III) chloride

Identity check: PCl₃ identifies phosphorus trichloride and is not phosphorus oxychloride (POCl₃).

Technical context: inorganic and organophosphorus synthesis

RFQ information: Before an RFQ, confirm the intended reaction route, water-exclusion and handling controls, offered form, and current specification.

Offered form: Not specified; confirm the actual offered form.

Specification review: Confirm identity, relevant assay or impurity criteria, and suitability in the current technical dossier.

Safety: Follow the current SDS for the exact offered form and the receiving site’s controls.

Packaging and documents: Confirm packaging and applicable documentation for the actual offered product.

FAQ - Technical & Supply Chain

  • Q:

    Are Phosphorus Trichloride, Phosphorus(III) Chloride and PCl₃ the same material?

    A: Yes. These names identify CAS 7719-12-2 and formula PCl₃. Do not confuse Phosphorus Trichloride with Phosphoryl Chloride, POCl₃, or Phosphorus Pentachloride, PCl₅. The purchase specification, label and analytical release should use the full identity because those chlorides are distinct materials and may also appear as process impurities.
  • Q:

    Which specifications should be agreed for Phosphorus Trichloride?

    A: Set assay and method, color, iron, Phosphoryl Chloride and other agreed phosphorus chloride impurities, plus water-reactivity or acidity-related controls appropriate to the process. Confirm whether the result is by titration, GC or another method. Compare the offered batch COA with the same specification and sampling basis.
  • Q:

    What must be agreed for bulk PCl₃ transport and unloading?

    A: PCl₃ reacts strongly with water and releases corrosive fumes. Agree a dry compatible tank, valve, gasket and closed-transfer system, inert-gas conditions, seal controls and allowable moisture exposure. Before dispatch, the receiving site should approve the current SDS, transport classification, unloading connection, scrubber or vapor-control arrangement and emergency response procedure.

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