(Triphenylphosphine)silver(I) Triflate, CAS 82888-97-9, is commonly represented as PPh3AgOTf or Ag(CF3SO3)(PPh3). The 1:1 formula unit is C19H15AgF3O3PS, with calculated molecular weight about 519.22 g/mol. Because silver-phosphine triflate materials can show coordination or aggregation differences, the formula basis, ligand-to-silver ratio, assay method and delivered form should be stated on the COA. Key controls include identity, free triphenylphosphine, silver salts, halide, water and light exposure.
(Triphenylphosphine)silver(I) Triflate (PPh3AgOTf) CAS 82888-97-9
- CAS: 82888-97-9
- Synonyms: (Triphenylphosphine)silver(I) triflate, Triphenylphosphine silver(I) triflate, PPh3AgOTf, Ag(OTf)(PPh3)
- Molecular Formula: C₁₉H₁₅AgF₃O₃PS
- Grade: Confirm identity by an appropriate analytical method, assay basis, related substances, residual solvents and storage requirements against the current COA; buyer qualification is required.
- Package: State required quantity and destination; confirm the current container material, closure or liner, net weight, product compatibility and transport conditions before quotation.
Product Description
Identity and physicochemical profile
| Item | Technical guidance |
|---|---|
| Product identity | (Triphenylphosphine)silver(I) triflate; PPh3AgOTf |
| CAS number | 82888-97-9 |
| 1:1 formula unit / calculated mass | C₁₉H₁₅AgF₃O₃PS / about 519.22 g/mol |
| Specification boundary | Formula basis, ligand-to-silver ratio and solid form must match the batch documentation |
| Key purchase controls | Identity, assay basis, Ag and P content, free PPh3, silver salts, halide, water, color and light exposure |
Applications and grade selection
This silver(I)-phosphine triflate material may be evaluated in coordination chemistry, controlled halide abstraction, catalyst preparation and organometallic research. Performance depends on stoichiometry, halide contamination, moisture, solvent and the actual ligand environment.
- Confirm the formula unit and ligand-to-silver ratio used for assay and molecular-weight reporting.
- Set limits for halide, free triphenylphosphine, silver salts, water and route-relevant impurities.
- Compare dissolution, reaction rate, selectivity and residue profile in the intended system.
Storage and handling
Keep sealed, dry and protected from light in compatible packaging under the current SDS and COA. Minimize repeated opening and record storage and sampling history during qualification.
Safety, documentation and procurement
Handle as a silver-containing organophosphine coordination material using suitable ventilation and personal protection. Procurement should define formula basis, assay, impurity limits, quantity, packaging, destination and waste requirements.
FAQ - Technical & Supply Chain
-
Q:
What should be confirmed when ordering PPh3AgOTf CAS 82888-97-9?
A: Confirm the 1:1 triphenylphosphine-to-silver triflate formula basis, molecular-weight basis and delivered form. The agreed release package should address identity, silver or ligand assay, free triphenylphosphine, residual silver salts, halide, water, solvent and light-protected packaging; do not substitute a differently ligated silver triflate complex.
Ordering & Documentation
Key information for document requests, quotations, and supply planning.
Documents
COA, TDS, SDS/MSDS and packing details are available on request.
Quotation
Send the CAS number, grade, quantity, packing preference and destination.
Sample & Supply
Support is available for samples, trial orders, bulk and repeat supply.
Storage & Shipping
Product-specific conditions are confirmed before order.



