Chemical products
  • Sodium Chlorite (NaClO2) CAS 7758-19-2
  • Sodium Chlorite (NaClO2) CAS 7758-19-2
  • Sodium Chlorite (NaClO2) CAS 7758-19-2

Sodium Chlorite (NaClO2) CAS 7758-19-2

Sodium Chlorite (NaClO2, CAS 7758-19-2, EC 231-836-6) is an oxidizing chemical used for controlled chlorine-dioxide generation, water treatment and bleaching processes. It is distinct from sodium hypochlorite, sodium chlorate and chlorine dioxide. Confirm active sodium chlorite content, impurities, physical form, dangerous-goods packaging and the intended activation process for the supplied grade. Handle strictly in accordance with the SDS.

  • CAS: 7758-19-2
  • Synonyms: Sodium chlorite, Chlorous acid sodium salt, NaClO2, Chlorite sodium salt
  • Einecs: 231-836-6
  • Molecular Formula: NaClO₂
  • Grade: Confirm active sodium chlorite content, moisture and impurity limits
  • Package: Confirm oxidizer-compatible packaging, transport classification and destination requirements
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Product Description

Product Overview

Sodium Chlorite (CAS 7758-19-2) is an inorganic chlorite oxidizer supplied in solid or aqueous grades for controlled industrial processes. It may be used to generate chlorine dioxide or in specified oxidation and bleaching systems only after concentration, process design, hazard controls and end-use authorization are confirmed.

Chemical identity alone does not establish suitability for drinking-water treatment, biocidal use, sanitation or a particular bleaching process. Confirm active sodium chlorite content, impurities, physical form, transport classification, required approvals and destination-market documentation for the offered grade.

Product Information / Specifications

Product Name Sodium Chlorite
CAS Number 7758-19-2
EINECS Number 231-836-6
Molecular Formula NaClO₂
Molecular Weight 90.44 g/mol
Form Confirm solid or solution form and the concentration basis for the offered product
Typical Grade Confirm active sodium chlorite content, moisture and impurity limits
Product Identity Industrial chemical / oxidizing agent

Physical & Chemical Properties

Appearance Appearance depends on solid or solution form; confirm against the offered grade
Solubility Soluble in water
Chemical Character Strong oxidizing substance
Reactivity Note May release chlorine dioxide or other hazardous gases on contact with acids or incompatible materials

Applications

  • Controlled chlorine-dioxide generation only for a validated process and an appropriately documented grade
  • Process oxidation in municipal or industrial treatment operations
  • Bleaching applications in sectors where chlorine dioxide chemistry is required
  • Odor control and sanitation-related treatment programs using controlled oxidizing systems
  • Selected industrial processing systems requiring chlorite-based oxidizing performance

Quality Control and Procurement Documents

For sodium chlorite procurement, specify the NaClO2 mass fraction and whether the result is reported as received or on a dry basis. Iodometric titration is used for sodium chlorite assay; ion chromatography can determine chlorate and sulfate impurities. Agree the analytical methods, reporting basis and impurity limits for the supplied solid or solution grade. A sodium chlorite assay is not the same quantity as available chlorine.

We can provide a Certificate of Analysis (COA), Technical Data Sheet (TDS), Safety Data Sheet (SDS) and relevant quality-control reports for sodium chlorite, including ion-chromatography results where applicable to the agreed specification.

Related Water-Treatment and Bleaching Materials

For water-treatment procurement, ferric chloride and polyaluminum chloride (PAC) serve as coagulants in separate treatment stages. They do not replace sodium chlorite as a chlorine-dioxide precursor; concentrated treatment chemicals must not be mixed together.

For comparison with peroxide-based bleaching materials, see sodium percarbonate and sodium perborate tetrahydrate. Their chemistry and process requirements differ from chlorite-based systems, so they are not direct replacements.

Packaging

Confirm oxidizer-compatible packaging, transport classification and destination requirements

Packaging information may vary by grade, purity range, destination, and regulatory handling requirements.

Storage Conditions

  • Store in a cool, dry, and well-ventilated area.
  • Keep container tightly closed and protected from moisture.
  • Keep away from acids, reducing agents, combustible materials, and organic substances.
  • Avoid heat exposure and conditions that may promote decomposition.
  • Use only compatible containers and handling systems suitable for oxidizing chemicals.

Safety Precautions

  • Handle as a strong oxidizer under appropriate industrial safety procedures.
  • Avoid inhalation of dust or mist and prevent contact with eyes, skin and clothing.
  • Use suitable protective gloves, eye protection, protective clothing, and ventilation.
  • Do not mix with acids, ammonia, reducing substances, or combustible materials.
  • Refer to the latest SDS before storage, handling, transport, or process use.

FAQ - Technical & Supply Chain

  • Q:

    Can Sodium Chlorite replace sodium hypochlorite or sodium chlorate in a treatment system?

    A: No. These are distinct oxidizing chemicals with different chemistry and compatibility requirements. Sodium Chlorite should be used only in the process for which it has been specified and validated. A substitution based on oxidizer name, active-content assumptions or equal dosage is not appropriate.
  • Q:

    Which Sodium Chlorite batch controls should match a validated chlorine-dioxide generation process?

    A: Confirm active sodium chlorite content, water, chloride, insoluble matter and the process-relevant impurity limits, together with test methods. The acceptance range should be aligned with the validated generation system and its written operating specification, rather than judged by assay alone.
  • Q:

    Does CAS 7758-19-2 alone confirm Sodium Chlorite suitability for drinking-water or biocidal use?

    A: No. CAS confirms chemical identity, not a regulated grade or authorized end use. Confirm active content, impurities, process design, required registration or approval, documentation and destination-market rules before procurement or use.

Ordering & Documentation

Key information for document requests, quotations, and supply planning.

Documents

Tell us which documents your procurement team needs. Before an order, we will check whether the quoted source can provide them for the offered lot.

Quotation

Send the CAS number, grade, quantity, packing preference and destination.

Sample & Supply

Ask whether samples, trial quantities or repeat orders are possible. We will check each request against the sourced product and current offer.

Storage & Shipping

Product-specific conditions are confirmed before order.

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For a quotation, please include the product name or CAS number, quantity, grade or application, and destination country or port. Tell us if you need a sample, COA, TDS or SDS.