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  • 1,4-Dioxane CAS 123-91-1

1,4-Dioxane CAS 123-91-1

1,4-Dioxane, CAS 123-91-1, is a cyclic ether and polar aprotic solvent used in controlled industrial and process applications. This page does not establish pharmaceutical-grade or consumer-product suitability. Confirm assay, water, peroxide value, acidity, nonvolatile residue, stabilization or storage requirements, packaging compatibility, and current TDS, COA, and SDS.

  • CAS: 123-91-1
  • Synonyms: p-Dioxane, 1,4-diethylene dioxide, Diethylene dioxide, Dioxane
  • Einecs: 204-661-8
  • Molecular Formula: C₄H₈O₂
  • Grade: Confirm assay, water, peroxide value, acidity, nonvolatile residue, and any stabilization or storage requirement
  • Package: Confirm packaging compatible with the offered liquid, transport classification, and destination requirements
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Product Description

Product name: 1,4-Dioxane

Recognized names: 1,4-Dioxane; p-Dioxane; diethylene dioxide; diethylene ether

Chemical identity: 1,4-Dioxane is a cyclic ether and polar aprotic solvent. It is used only in controlled industrial and process settings; this page does not establish pharmaceutical grade or consumer-product suitability.

CAS Number: 123-91-1

EINECS accession number: 204-661-8

Chemical formula: C₄H₈O₂

Molar mass: 88.11 g/mol

Melting point: 12 °C

Boiling point: 101 °C

Water solubility: miscible with water

Density: 1.033 g/cm³

Flash point: 12 °C

Technical use: solvent or process medium for selected resins, oils, waxes, and controlled chemical synthesis. Suitability must be assessed against the buyer’s process, impurity limits, exposure controls, and destination requirements.

Offered specification: confirm assay, water, peroxide value, acidity, nonvolatile residue, and stabilization or storage requirements

Packaging: confirm a compatible package for the offered solvent, transport classification, and destination requirements

FAQ - Technical & Supply Chain

  • Q:

    Are 1,4-Dioxane and 1,3-Dioxolane interchangeable solvents?

    A: No. 1,4-dioxane is CAS 123-91-1, while 1,3-dioxolane is a different cyclic acetal with a different CAS number and reactivity. Confirm the full name, CAS number, water content and stabilizer or inhibitor status before approving a substitute solvent.
  • Q:

    Which release specifications matter for 1,4-Dioxane?

    A: Agree GC assay, water, peroxide value, aldehydes, acidity, nonvolatile residue, color and relevant ether or glycol-ether impurities. Peroxide control is important because ethers can form peroxides during storage. The COA should state the test methods, production date and whether the result is for stabilized material.
  • Q:

    What must be checked for bulk 1,4-Dioxane handling?

    A: Confirm the approved package, seals, previous-cargo cleanliness, vapor control, grounding, ventilation and receiving-tank capacity. Check the current SDS and destination transport requirements before shipment. Avoid prolonged storage, contamination and heat, and document peroxide testing and container-opening controls at the receiving site.

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