Pentaerythritol Oleate, commonly abbreviated as PETO and chemically identified as Pentaerythritol Tetraoleate under CAS 19321-40-5, is a premium synthetic polyol ester derived from the esterification of pentaerythritol and oleic acid. This product is a viscous, biodegradable liquid recognized for its exceptional thermal and oxidative stability, high viscosity index, and superior lubricity. It serves as a critical base stock (Group V base oil) in the formulation of fire-resistant hydraulic fluids, air compressor oils, and environmentally acceptable lubricants (EALs). Unlike mineral oils, PETO offers a low pour point and high flash point, making it ideal for demanding industrial environments. We ensure bulk supply with competitive factory pricing for industrial clients. Our inventory is managed to support customized specifications (such as specific acid value or color requirements), and every shipment is accompanied by complete MSDS, TDS, COA documentation.
Pentaerythritol Oleate (PETO) CAS 19321-40-5
- CAS: 19321-40-5
- Synonyms: Pentaerythritol Tetraoleate, PETO Ester, Synthetic Polyol Ester, 2,2-Bis[[(1-oxo-9-octadecenyl)oxy]methyl]-1,3-propanediyl bis(9-octadecenoate), Bio-based Lubricant Base Stock, POE Lubricant.
- Einecs: 242-960-5
- Molecular Formula: C₇₇H₁₄₀O₈
- Grade: Industrial grade 99%
- Package: 200kg iron drum or 50kg plastic drum packaging
Product Description
Physicochemical properties
| Property | Description |
|---|---|
| Molecular Weight | 1193.9307 |
| Appearance | Light yellow transparent liquid (industrial products are usually colorless or yellow transparent liquids) |
| Density (g/cm³) | 0.926-0.935 (at 25℃) |
| Viscosity (mm²/s) | 68.3 (at 40℃), 12.5 (at 100℃) |
| Viscosity Index | ≥180 |
| Acid Value (mgKOH/g) | ≤1.0 (some products ≤3.0) |
| Saponification Value (mgKOH/g) | 187-190 |
| Flash Point (℃) | ≥300 (opening flash point, some data indicates 342.9℃ or 343.088℃) |
| Pour Point (℃) | ≤-32 (some data indicates ≤-25℃) |
| Boiling Point (℃) | 996.0±65.0 (predicted value at 760 mmHg) |
| Solubility | Soluble in many organic solvents |
| Biodegradability | Biodegradable, with a biodegradation rate of over 90% |
| Stability | Good hydrolysis stability, high flash point, low volatility, and excellent low-temperature characteristics |
Application Areas
Lubrication field: Pentaerythritol oleate is an ideal base oil for No. 68 synthetic ester-based fire-resistant hydraulic oil. It can also be used to formulate environmentally friendly hydraulic oil, chain saw oil, and watercraft engine oil. As an oiliness agent, it is widely used in steel plate cold rolling fluids, steel pipe drawing oils, and other metalworking fluids.
Plastic processing: Used as an anti-fogging agent, antistatic agent, lubricant, and mold release agent in PVC processing. It can also be used in soft and hard PVC sheets, plates, profiles, pipes, transparent bottle materials, and heat-shrinkable films.
Other fields: It can also be used as an intermediate for textile and leather auxiliaries, textile oil agents, as well as an organic synthesis intermediate for cosmetics and pharmaceuticals.
Storage conditions
environmental condition
Temperature: Store in a cool, well-ventilated area and avoid high temperatures (recommended temperature ≤30-34℃, some data indicate a melting point of 30-34℃, and precautions should be taken to prevent solidification or decomposition).
Light exposure: Keep away from direct sunlight to prevent ultraviolet rays from accelerating product degradation.
Humidity: Keep the environment dry to prevent moisture (recommended relative humidity ≤60%).
Container requirements
Store in the original packaging (such as iron drums or plastic drums) and ensure the container is sealed and free from damage or leakage.
The container label must clearly indicate the name of the chemical, CAS number (19321-40-5), hazard identification (such as flammable, irritant), and production date.
Isolation storage
Keep away from oxidants, reducing agents, strong acids and alkalis, as well as sources of ignition, to avoid chemical reactions or fire risks.
The storage area needs to be equipped with leak-proof trays or cofferdams to prevent the spread of leaks.
Safety precautions
Specification for use process
Avoid high temperatures: Keep away from open flames, hot surfaces, and sparks to prevent the accumulation of flammable vapors that could lead to explosions (flash point ≥300℃, but caution is still required).
Prevent splashing: When pouring or transferring, operate slowly to avoid splashing the liquid onto the skin or eyes.
Concentration control: Use the product according to the recommended ratio stated in the product manual to avoid performance degradation or safety hazards caused by overuse.
Fire protection measures
Fire extinguishing method: Use dry powder, carbon dioxide, or foam extinguishers. Do not spray water directly (may cause spreading fire).
Fire Risk: May release irritating fumes at high temperatures. Wear self-contained breathing apparatus (SCBA) and full protective clothing when extinguishing fires.
FAQ - Technical & Supply Chain
-
Q:
What are the main advantages of Pentaerythritol Oleate (PETO) over mineral oils?
A: PETO offers significantly higher thermal stability, a higher flash point (improving safety), and a naturally high viscosity index (meaning its viscosity changes less with temperature). Additionally, CAS 19321-40-5 is biodegradable, making it the preferred choice for environmentally sensitive applications like forestry or marine hydraulics. -
Q:
Can PETO be used as a standalone lubricant?
A: It is typically used as a base stock (base oil) or an additive. Formulators blend it with antioxidants, anti-wear agents, and corrosion inhibitors to create finished lubricants. It is also used as a lubricity additive in metalworking fluids.
Documents and Product Support
For product review and sourcing evaluation, supporting documents can be coordinated according to the product type, inquiry stage, and order requirements.
- COA for batch-based quality reference
- TDS for key physical and chemical information
- SDS / MSDS for handling, storage, and safety reference
- Packing information for sample, trial, and bulk orders
- Technical communication based on application and specification requirements
Information to Confirm Before Quotation
Clear sourcing information helps reduce specification mismatch and allows a more accurate quotation before sample or bulk order discussion.
- Product name and CAS number
- Application or intended end use
- Required purity, grade, or specification
- Sample quantity, trial order, or bulk demand
- Preferred packing form or net weight
- Destination country or port
- Required documents or compliance expectations
Packaging, Storage, and Handling Notes
Packaging form, storage conditions, shelf life, and shipment arrangements should be confirmed according to the product characteristics, package size, and destination requirements.
Before order confirmation, buyers are advised to review the corresponding product documents and confirm whether any special storage, labeling, or handling requirements apply.
Sample, Bulk Order and Repeat Supply Support
Support can be arranged for sample discussion, bulk supply planning, packaging confirmation, and routine sourcing communication based on the actual product and order requirements.
For repeat-use formulations or long-term procurement plans, buyers may discuss specification consistency, packaging preferences, delivery expectations, and document coordination in advance.






